50 cal of heat should be supplied to take a system from the state A to the state B through the path ACB as shown in figure. Find the quantity of heat to be supplied to take it from A to B via ADB.
In path ACB,
ΔQ=50 cal=(50×4.2) J
=210 J
ΔW=WAC+WCB
=50×10−3×200×10−6
=10 J
ΔQ=ΔU+ΔW
⇒ΔU=ΔQ−ΔW=(210−10) J
=200 J
In path ADB, ΔQ=?
ΔU=200 J
(Internal energy change between two points is always same)
ΔW=WAD+WDB=ΔW
=0+155×103×200×10−6
=31 J
ΔQ=ΔU+ΔW
=200+31 J=231 J
=55 cal.