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Question

50 cal of heat should be supplied to take a system from the state A to the state B through the path ACB as shown in figure. Find the quantity of heat to be supplied to take it from A to B via ADB.

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Solution

In path ACB,

ΔQ=50 cal=(50×4.2) J

=210 J

ΔW=WAC+WCB

=50×103×200×106

=10 J

ΔQ=ΔU+ΔW

ΔU=ΔQΔW=(21010) J

=200 J

In path ADB, ΔQ=?

ΔU=200 J

(Internal energy change between two points is always same)

ΔW=WAD+WDB=ΔW

=0+155×103×200×106

=31 J

ΔQ=ΔU+ΔW

=200+31 J=231 J

=55 cal.


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