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Question

6 g urea sample on heating with NaOH gives 0.224 L NH3 at STP.
NH2CONH2+2NaOH2NH3+Na2CO3
Thus, percentage yield of NH3 is :

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Solution

The molar mass of urea is 60 g/mol.
6 g of urea corresponds to 660=0.1 moles.
They will produce 0.2 moles of ammonia which will occupy a volume of 22.4×0.2=4.48 L.
Hence, the percentage yield is 0.2244.48×100=5%.

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