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Question

A certain weight of pure CaCO3is made to react completely with 200 mL of an HCl solution to give 224 mL of CO2gas at STP. The normality of the HCl is

A

0.05 N

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B

0.1 N

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C

1.0 N

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D

0.2 N

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Solution

The correct option is B: 0.1 N

CaCo3+2HCl CaCl2+ H2O+CO2

The most common example is the molar volume of a gas at STP (Standard Temperature and Pressure), which is equal to 22.4 L for 1 mole of any ideal gas at a temperature equal to 273.15 K and a pressure equal to 1.00 atm.

We know that number of moles = Given mass /Molar mass

nCO2=22422400 = 102

nHCl =2nCO2 = 2 × 102

WKT

N1V1=N2V2

For a monobasic acid, molarity = Normality

So, 200× NHCl1000 = 2× 102

NHCl =0.1N


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