The correct option is D Bordeaux mixture
Bordeaux mixture has been used for ages as an effective fungicide. This fungicide is so called 'holy water of plant pathology' which was first discovered by Prof. Millardet of Bordeaux university. Bordeaux comprises copper sulphate, lime and water and is ideal as a winter fungicide as it can adhere to plants in rainy climate. Being an effective fungicide against white rust, mildews and blights gives a long lasting protection to plants.