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Nomenclature of Coordination Compounds

A compound of...

Question

A compound of platinum, ammonia and chlorine produces which complex compound?

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Solution

The compound of platinum,ammonia and chlorine produces four ions per molecule in the solution.The structure consist after observation is
$[P t (N H_{3})_{5} C l] C l_{3}$ .

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P t

complex of ammonia and chlorine produces four ions per molecule in the solution is

Q. A coordination complex compound of cobalt has the molecuar formula containing five ammonia molecules, one nitro group and two chlorine atoms for one cobalt atom. One mole of this compound produces three moles of ions in an aqueous solution. On the addition of silver nitrate, two moles of

A g C l

are precipitated. The ionic formula for this complex would be:

Q. An organic compound (A) on heating produces two gases (B) and (C) and neutral oxide (D) which turns cobalt chloride paper pink. Gas (B) turns lime water milky and produces an acidic solution, with water. Gas (C) produces a poisonous gas (E) with chlorine gas, this gas with ammonia gives an organic compound (F) which on further reaction with (D) gives

N H_{3}

gas. Then, compounds (A) and (F) can be found as:

Q. A complex of platinum, ammonia and chloride produces four ions per molecule in the solution. The structure consistent with the observation is :

The platinum-chlorine distance has been found to be 2.32

A^{\circ}

in several crystalline compounds. This value applies to both of the compounds shown in the figure.

A

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