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Question

A mixture of three amines A, B and C is treated with Benzene sulphonyl chloride and filtered.' B' is obtained in the filterate. The mixture containing A and C is treated with KOH so that' A' becomes soluble while 'C' does not. Now A, B and C are


A

Aliphatic primary, secondary and tertiary

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B

Aliphatic secondary, tertiary and primary

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C

Aliphatic primary, tertiary and secondary

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D

Aliphatic tertiary, secondary and primary

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Solution

The correct option is C

Aliphatic primary, tertiary and secondary


B is 30 amine as it is not reacting with benzene sulphonyl chloride; A is 10amine as the product is soluble in KOH; C is 20 amine


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