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Question

A sample of chloroform before being used as an anaesthetic agent is tested by


A

Febling's solution

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B

Ammonical cuprous chloride

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C

Silver nitrate solution in the cold

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D

Silver nitrate solution after boiling with alcoholic KOH

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Solution

The correct option is C

Silver nitrate solution in the cold


If CHCl3 sample contains phosgene (COCl2 ) then it will give a white ppt. When treated with

AgNO3 solution in the cold.

However, after boiling CHCl3 with alcoholic KOH , the resulting solution will always give white ppt.

with AgNO3 solution whether it contains( COCl2 ) or not.


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