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Question

A solution of colourless salt 'S' on boiling with excess NaOH produces a non-flammable gas. The evolution of the gas ceases after sometime. Upon addition of Zn dust to the same solution, the gas is evolved again. The colourless salt(s) 'S' can be:

A
NH4NO3
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B
NH4NO2
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C
NH4Cl
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D
(NH4)2SO4
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Solution

The correct options are
A NH4NO3
B NH4NO2
NH4NO3+NaOHNH3+NaNO3+H2O
7NaOH+NaNO3+4Zn4Na2ZnO2+NH3+2H2O

NH4NO2+NaOHNaNO2+NH3+H2O
3Zn+5NaOH+NaNO23Na2ZnO2+NH3+H2O

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