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Question

A solution of sucrose (molar mass = 342 g/mol) is prepared by dissolving 68.4 g of it per litre of the solution. What is its osmotic pressure (R = 0.082 lit. atm.k-1mol-1) at 273 K?

A

6.02 atm

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B

4.92 atm

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C

4.04 atm

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D

5.32 atm

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Solution

Weight given (sucrose) = 68.4 gram

Gas constant (R) = 0.082 lit. atm.K1 mol1

Temperature = 273 K

Molecular mass = 342 gm/mol

V = 1

Hence using the formula of osmotic pressure we get

π=w×R×Tmolarmass×Volume

π=68.4×0.082×273342

π=4.48atm





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