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Question

According to molecular orbital theory, which of the following will not exist?

A
H+2
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B
Be2
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C
B2
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D
C2
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Solution

The correct option is B Be2
According to the molecular orbital theory elements which have bond order negative or 0 will not exist.

Formula to calculate bond order =Number of electrons in BMONumber of electrons in ABMO2

where, BMO= Bonding molecular orbital
ABMO= Antibonding molecular orbital

Molecular electronic configuation of Be2=σ1s2σ1s2σ2s2σ2s2

Be2 has 4 electrons in BMO and 4 in ABMO so the bond order will come 0.

So, the correct option is [B].

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