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Question

Al+MnO4Al(OH)4+MnO2
For the above reaction , the oxidation state of Al and Mn in the reactant are respectively:

A
0 and +7
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B
+2 and +7
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C
0 and +6
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D
+1 and +7
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Solution

The correct option is B 0 and +7
Al+MnO4Al(OH)4+MnO2
-The oxidation number of an element in its free (uncombined) state is zero.
So the oxidation state of Al is =0 at reactant side.
-The sum of all oxidation numbers in a polyatomic (many-atom) ion is equal to the charge on the ion. The oxidation number of oxygen in a compound is usually 2. Therefore the oxidation state ofMn in MnO4 is
x+4(2)=1
x=+7

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