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Question

Arrange the following alkanes in decreasing order of their heats of combustion.
(i) CH3−CH3|C|CH3−CH3(Neo−pentane)

(ii) CH3−CH|CH3−CH2−CH3(Iso−pentane)
(iii)CH3−CH2−CH2−CH2−CH3(n−pentane)

A
(i) > (ii) > (iii)
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B
(iii) > (I) > (ii)
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C
(iii) > (ii) > (i)
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D
(i) > (iii) > (ii)
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Solution

The correct option is C (iii) > (ii) > (i)
CH3
H3C|C|CH3 CH3CH|CH2CH3 CH3CH2CH2CH2CH3
CH3 CH3
Neopentane(i) Isopentane(ii) npentane(iii)

We know that alkanes that are more branched, have less heat of combustion than a less branch one. Thus here heat of combustion order will be:
npentane(iii)>isopentane(ii)>Neopentane(i).

Because here Neopentane is more branched than isopentane which is again more branched than npentane.

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