Calculate the entropy change accompanying the following change of state
5 mol of O2(27∘C,1atm) → 5mol of O2(117∘C,5atm)
CP for O2 = 6.95 cal deg−1 mol−1
Here lets devide the process in 2 stages
Δ S1 → 5 mol of O2 (1atm) → 5 mol of O2 (5atm)
ΔS2 → T → 27∘ to 117∘C
Now,
ΔS1=qrevT=−WrevT=1T×∫V2V1 P dV
= 1T.nRT ∫V2V1 dVV = nR × 2.303 log V2V1
= 5 × 1.987 × 2.303 log P1P2
= 5 × 1.987 Δ2.303 log 15 = −16.0 cal deg−1
ΔS2 = for the change of temperature from 27∘C to 117∘C
ΔS2 = nCP ∫T2T1 dTT
= 5 × 6.95 × 2.303 log390300
= 5 × 6.95 × 2.303 × 0.1139
= 9.12 cal deg−1
ΔS = −16.0 + 9.12 = −6.88 cal deg−1