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Question

Calculate the entropy change accompanying the following change of state

5 mol of O2(27C,1atm) 5mol of O2(117C,5atm)

CP for O2 = 6.95 cal deg1 mol1


A
8.88 cal deg1
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B
6.88 cal deg1
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C
9.77 cal deg1
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D
10.77 cal deg1
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Solution

The correct option is B 6.88 cal deg1

Here lets devide the process in 2 stages

Δ S1 5 mol of O2 (1atm) 5 mol of O2 (5atm)

ΔS2 T 27 to 117C

Now,

ΔS1=qrevT=WrevT=1T×V2V1 P dV

= 1T.nRT V2V1 dVV = nR × 2.303 log V2V1

= 5 × 1.987 × 2.303 log P1P2

= 5 × 1.987 Δ2.303 log 15 = 16.0 cal deg1

ΔS2 = for the change of temperature from 27C to 117C

ΔS2 = nCP T2T1 dTT

= 5 × 6.95 × 2.303 log390300

= 5 × 6.95 × 2.303 × 0.1139

= 9.12 cal deg1

ΔS = 16.0 + 9.12 = 6.88 cal deg1


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