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Question

Calculate the number of moles of KMnO4 that will be neded to react completely with one mole of ferrous oxalate Fe(C2O4) in acidic solution is:

A
2/5
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B
3/5
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C
6/5
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D
2
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Solution

The correct option is B 3/5
3 MnO4+5(Fe2++C2O24)+24 H+3 Mn2++5Fe3++10CO2+12H2O

Thus 5 M of FeC2O4 is oxidised by 3 M of KMnO4 then 1 M of FeC2O4 is oxidised by 3/5 mole of KMnO4.

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