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Question

Calucalculate standard entropy change in the reaction

Fe2O3(s) + 3H2(g) 2Fe(s) + 2H2O(1)

Given: Som(Fe2O3,S) = 87.4, Som(Fe,S) = 27.3

Som(H2,g) = 130.7, Som(H2O,1)= 69.9 JK1mol2


A

-212.5 JK-1

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B

-215.2 JK-1

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C

-120.9 JK-1

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D

None of these

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Solution

The correct option is B

-215.2 JK-1


Fe2O3(s) + 3H2(g) 2Fe(s) + 3H2O(s)

Changed balanced equation

ΔS = S0(Products) S0(Reactants)

[2S0Fe + 2S0H2O] [S0Fe2O3 + 3S0H2]

= (2 × 27.3 + 3 × 69.9) [87.4 + 3 × 130.7] = (54.6 + 209.7) [87.4 + 92.1]

= 264.3 479.5 = 215.2 J/K/mol


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