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Question

CH3−CH2−CH2−CH2−CH3|C|CH3−CH2−CH2−OHH+−−→Δ(A)(major)
Product (A) is:

A
CH3CH2CH2CH2C|CH3=CHCH3
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B
CH3(CH2)3C(CH3)=C(CH3)2
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C
CH3CH2CH2CH2C|CH3=CH2
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D
CH3CH2CH|CH3CH2CH3|C=CH2
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Solution

The correct option is B CH3(CH2)3C(CH3)=C(CH3)2

Carbocation rearrangement in acidic medium takes as shown

refer to image

order of stability of carbocation – teritiary>secondary>primary

More substituted alkene will formed as major product.

Option B is correct.


1120956_990285_ans_b71adb2ff1e64e67bf01e340e0b67ccb.png

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