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Question

CH3CH3 CD3CD3 CH3CH3|C|CH3CH3
(I) (II) (III)
Correct order of rate of photochlorination for following compounds is :

A
II < I < III
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B
I < II < III
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C
III < I < II
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D
II < III < I
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Solution

The correct option is A II < I < III
Photochlorination depends upon bond strength of C-H bond, as C-D bond is stronger than C-H so its reactivity will be least. and compound III has highest reactivity due to formation of stable intermediate.

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