CH2-CH-Ch2Cl and CH3-CH2-Cl which is more reactive towards SN1 nbsp-reaction-

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Reduction of Carboxylic Acids

CH2=CH-Ch2Cl ...

Question

CH2=CH-Ch2Cl and CH3-CH2-Cl which is more reactive towards SN1 reaction'?

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\begin{matrix} C H_{3} - & C H & - C H_{2} - C l | C H_{3} \end{matrix}

\begin{matrix} C H_{3} - C H_{2} - & C H & - C l | C H_{3} \end{matrix}

S_{N} 1

S_{N} 2

K I

C H_{3} - C H_{2} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H ∣ C H_{3} - C H_{2} - C l

(I) (I I)

C H_{3} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H_{2} - C H_{2} - B r

(I) (I I)

C H_{3} - C H ∣ C H_{3} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H_{3} ∣ C ∣ C H_{3} - C H_{2} C l

(I) (I I)

C H_{3} - C H_{2} - C H_{2} - B r ∣ C H - C H_{3} a n d C H_{3} - C H_{3} ∣ C H - C H_{2} - B r ∣ C H - C H_{3}

(I) (I I)

S_{N} 1

C H_{3} X, C H_{3} - C H_{2} - X, C H_{3} - C | X H - C H_{3}, C H_{3} - C H_{3} | C | C H_{3} - X,

(X = S a m e)

A, B

C

S_{N} 1

C H_{3} - C H_{2} - C H_{2} - B r

C H_{3} - C H - C H_{3}

B r

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