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Question

Choose the correct order for HOCl,HClO2,HClO3 and HClO4:

A
Oxidation state of halogen atom: HOCl<HClO2<HClO3<HClO4
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B
Oxidising power: HOCl>HClO2>HClO3>HClO4
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C
Acid strength: HOCl<HClO2<HClO3<HClO4
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D
Thermal stability: HOCl<HClO2<HClO3<HClO4
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E
s-character in hybrid state: HOCl<HClO2<HClO3<HClO4
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Solution

The correct options are
A Thermal stability: HOCl<HClO2<HClO3<HClO4
C Oxidation state of halogen atom: HOCl<HClO2<HClO3<HClO4
E Acid strength: HOCl<HClO2<HClO3<HClO4
(a) HOCl<HClO2<HClO3<HClO4
Oxidation states of Cl in HClO47
Oxidation states of Cl in HClO35
Oxidation states of Cl in HClO23
Oxidation states of Cl in HOCl1
(b) HOCl<HClO2<HClO3<HClO4
Acid with higher oxidation number is more capable of oxidising other species.
(c) HOCl<HClO2<HClO3<HClO4
Higher the oxidation number more is the acidity.
(d) HOCl<HClO2<HClO3<HClO4
(e) Equal (25%) each Cl-atom is sp3 hybridised.

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