Choose the correct order for HOCl,HClO2,HClO3 and HClO4:
A
Oxidation state of halogen atom: HOCl<HClO2<HClO3<HClO4
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B
Oxidising power: HOCl>HClO2>HClO3>HClO4
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C
Acid strength: HOCl<HClO2<HClO3<HClO4
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D
Thermal stability: HOCl<HClO2<HClO3<HClO4
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E
s-character in hybrid state: HOCl<HClO2<HClO3<HClO4
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Solution
The correct options are A Thermal stability: HOCl<HClO2<HClO3<HClO4 C Oxidation state of halogen atom: HOCl<HClO2<HClO3<HClO4 E Acid strength: HOCl<HClO2<HClO3<HClO4 (a) HOCl<HClO2<HClO3<HClO4 Oxidation states of Cl in HClO4−7 Oxidation states of Cl in HClO3−5 Oxidation states of Cl in HClO2−3 Oxidation states of Cl in HOCl−1 (b) HOCl<HClO2<HClO3<HClO4 Acid with higher oxidation number is more capable of oxidising other species. (c) HOCl<HClO2<HClO3<HClO4 Higher the oxidation number more is the acidity. (d) HOCl<HClO2<HClO3<HClO4 (e) Equal (25%) each Cl-atom is sp3 hybridised.