Synthesis of Aldehydes and Ketones Using Carboxylic Acid and Its Derivatives
Compound A re...
Question
Compound A reacts with PCl5 to give B which on treatment with KCN followed by hydrolysis gave propionic acid. A & B are respectively:
A
C3H8andC3H7Cl
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B
C2H6andC2H5Cl
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C
C2H5andC2H4Cl2
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D
C2H5OHandC2H5Cl
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Solution
The correct option is DC2H5OHandC2H5Cl Here, first an alkyl halide is formed upon reaction with phosphorus pentachloride which then converts into cyanide on reaction with KCN and then finally an acid is formed upon hydrolysis.