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Question

Compound A reacts with PCl5 to give B which on treatment with KCN followed by hydrolysis gave propionic acid. A & B are respectively:

A
C3H8andC3H7Cl
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B
C2H6andC2H5Cl
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C
C2H5andC2H4Cl2
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D
C2H5OHandC2H5Cl
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Solution

The correct option is D C2H5OHandC2H5Cl
Here, first an alkyl halide is formed upon reaction with phosphorus pentachloride which then converts into cyanide on reaction with KCN and then finally an acid is formed upon hydrolysis.
The reaction of process is as shown.

127090_14535_ans.png

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