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Introduction and Degree of Hydrolysis

Consider the ...

Question

Consider the reactions
$(i) C O (g) + H_{2} O (g) ⇌ C O_{2} (g) + H_{2} (g); K_{1} (i i) C H_{4} (g) + H_{2} O (g) ⇌ C O (g) + 3 H_{2} (g); K_{2} (i i i) C H_{4} (g) + 2 H_{2} O (g) ⇌ C O_{2} (g) + 4 H_{2} (g); K_{3}$
which of the following is correct?

K_{3} = K_{1} / K_{2}

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K_{3} = K_{1}^{2} / K_{2}^{3 -}

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K_{3} = K_{1} K_{2}

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K_{3} = K_{1} \sqrt{K_{2}}

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Solution

The correct option is C $K_{3} = K_{1} K_{2}$
$C O (g) + H_{2} O (g) ⇌ C O_{2} (g) + H_{2} (g); K_{1} - - - - - - (i) C H_{4} (g) + H_{2} O (g) ⇌ C O (g) + 3 H_{2} (g); K_{2} - - - - - (i i)$
Adding (i) and (ii) we get;
$C H_{4} (g) + 2 H_{2} O (g) ⇌ C O_{2} (g) + N H_{2} (g); K_{3} S o, K_{3} = K_{1} K_{2}$

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Similar questions

(i) C O (g) + H_{2} O (g) ⇌ C O_{2} (g) + H_{2} (g); K_{1} (i i) C H_{4} (g) + H_{2} O (g) ⇌ C O (g) + 3 H_{2} (g); K_{2} (i i i) C H_{4} (g) + 2 H_{2} O (g) ⇌ C O_{2} (g) + 4 H_{2} (g); K_{3}

C O (g) + H_{2} O (g) ⇌ {C O}_{2} (g) + H_{2} (g); K_{1}

{C H}_{4} (g) + H_{2} O (g) ⇌ C O (g) + 3 H_{2} (g); K_{2}

{C H}_{4} (g) + 2 H_{2} O (g) ⇌ {C O}_{2} (g) + {4 H}_{2} (g); K_{3}

C O (g) + H_{2} O (g) ⇋ C O_{2} (g) + H_{2} (g); K_{1}

C H_{4} (g) + H_{2} O (g) ⇋ C O (g) + 3 H_{2} (g); K_{2}

C H_{4} (g) + 2 H_{2} O (g) ⇋ C O_{2} (g) + 4 H_{2} (g); K_{3}

C O (g)

+ H_{2} O (g) ⇋ C O_{2} (g) + H_{2} (g); K_{1}

C H_{4} (g) + H_{2} O (g) ⇋ C O (g) + 3 H_{2} (g); K_{2}

C H_{4} (g) + 2 H_{2} O (g) ⇋ C O_{2} (g) + 4 H_{2} (g); K_{3}

C O

(g) + H_{2} O (g) ⇌ C O_{2} (g) + H_{2} (g)

K_{1}

C H_{4} (g) + H_{2} O (g) ⇌ C O (g) + 3 H_{2} (g); K_{2}

C H_{4} (g) + 2 H_{2} O (g) ⇌ C O_{2} (g) + 4 H_{2} (g); K_{3}

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