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Question

Describe the change in hybridisation of the Al atom in the following reaction :

AlCl3+ClAlCl4

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Solution

The hybridization of Al atom changes from sp2 in AlCl3 to sp3 in AlCl4.

In AlCl3, Al contains 3 bond pairs of electrons and zero lone pair of electrons.

Hence, it is sp2 hybridized. In AlCl4, Al atom contains 4 bond pairs of electrons and zero lone pairs of electrons.

Hence, it is sp3 hybridized.

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