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Question

Determine the osmotic pressure of a solution prepared by dissolving 2.5 × 102g of K2SO4 in 2L of water at 25, assuming that it is completely dissociated.
(R = 0.0821 L atm K1 mol1, Molar mass of K2SO4 = 174 g mol1).

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Solution

Concentration (C)=MolesVolume=2.5×1031742=7.183×105M
R=0.0821 L atm K1 mol1 and T=298K.
Osmotic pressure (π)=CRT=7.183×105×0.0821×298
Osmotic pressure (π)=1.75×103atm

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