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Byju's Answer
Standard XII
Chemistry
Redox Reactions and Couple
Eo values for...
Question
E
o
values for the half cell reactions are given:
C
u
2
+
+
e
−
→
C
u
+
;
E
o
=
0.15
V
C
u
2
+
+
2
e
−
→
C
u
;
E
o
=
0.34
V
What will be the
E
o
of the half-cell:
C
u
+
+
e
−
→
C
u
?
A
+
0.49
V
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B
+
0.19
V
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C
+
0.53
V
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D
+
0.30
V
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Solution
The correct option is
D
+
0.53
V
Given,
C
u
2
+
+
e
−
→
C
u
+
;
E
0
1
=
0.15
V
,
Δ
G
0
1
,
n
1
=
1
C
u
2
+
+
2
e
−
→
C
u
;
E
0
2
=
0.34
V
,
Δ
G
0
2
,
n
2
=
2
C
u
+
+
e
−
→
C
u
;
E
0
3
=
?
V
,
Δ
G
0
3
,
n
3
=
1
As
Δ
G
is an extensive property,
Δ
G
0
3
=
Δ
G
0
2
−
Δ
G
0
1
⟹
−
n
3
F
E
0
3
=
−
n
2
F
E
0
2
+
n
1
F
E
0
1
−
E
0
3
=
−
2
×
0.34
+
1
×
0.15
E
0
3
=
0.68
−
0.15
=
0.53
V
Hence, option C is correct.
Suggest Corrections
0
Similar questions
Q.
Given,
C
u
2
+
+
2
e
−
→
C
u
;
E
o
=
0.337
V
C
u
2
+
+
e
−
→
C
u
+
;
E
o
=
−
0.153
V
E
o
value for the reaction,
C
u
+
+
e
→
C
u
will be:
Q.
If for the half-cell reactions
C
u
2
+
+
e
−
⟶
C
u
+
E
o
=
0.15
V
C
u
2
+
+
2
e
−
⟶
C
u
E
o
=
0.34
V
Calculate
E
o
of the half cell reaction
C
u
+
+
e
−
⟶
C
u
Also predict whether
C
u
+
undergoes disproportionation or not.
Q.
If for the half cell reactions
C
u
2
+
+
e
−
→
C
u
+
E
o
=
0.15
V
C
u
2
+
+
2
e
−
→
C
u
E
o
=
0.34
V
Calculate
E
o
of the half cell reaction
C
u
+
+
e
−
→
C
u
also predict whether
C
u
+
undergoes disproportionation or not.
Q.
Given (i)
C
u
2
+
+
2
e
−
→
C
u
,
E
o
=
+
0.337
V
(ii)
C
u
2
+
+
e
−
→
C
u
+
E
o
=
+
0.153
V
Electrode potential,
E
0
for the reaction will be:
C
u
+
+
e
−
→
C
u
Q.
C
u
+
+
e
−
⟶
C
u
,
E
o
=
x
1
volt ;
C
u
2
+
+
2
e
−
⟶
C
u
,
E
o
=
x
2
volt, then for
C
u
+
+
e
−
⟶
C
u
+
,
E
o
(volt) will be :
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