In SF6, one electron each from 3s and 3p orbitals is promoted to 3d orbitals The six orbitals get hybridized to form six sp3d2 hybrid orbitals. Each of these sp3d2 hybrid orbitals overlaps with 2p orbital of fluorine to form S–F bond.
Thus, SF6 molecule has octahedral structure. The dotted electrons represent electrons from F–atoms.