Enthalpy of neutralisation of the reaction between CH3COOH(aq.) and NaOH(aq.) is −13.2kcaleq−1 and that of the reaction between H2OS4(aq.) and KOH(aq.) is 13.7kcaleq−1. The enthalpy of dissociation of CH3COOH(aq.) is___________.
A
−0.5kcaleq−1
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B
+0.5kcaleq−1
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C
−26.9caleq−1
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D
+13.45kcaleq−1
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Solution
The correct option is A+0.5kcaleq−1 Dissociation enthalpy of CH3COOH=13.2−13.7=0.5kcaleq−1