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Question

Fluorine exhibits only 1 oxidation state whereas other halogens exhibit +1,+3,+5 and +7 oxidation states also. Explain.

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Solution

Oxidation states of halogens

Fluorine is the most electronegative element, so it cannot exhibit any positive oxidation state and also it does not have d orbitals in its valence shell, so it cannot expand their octet.

Other halogens have d orbitals, therefore, they can expand their octets and they can show +1,+3,+5 and +7 oxidation states also.

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