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Question

Fluorine shows only +1, 1 oxidation state while other halogen element shows +3, +5 and +7 oxidation states in addition to +1, 1. Why?

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Solution

Fluorine is the most electronegative element of the periodic table. It always exhibits 1 and +1 oxidation state but other halogens show 1, +1, +3, +5 and +7 oxidation states. They show a high oxidation state in the presence of vacant d-orbital. But fluorine has no vacant d-orbital so it does not show a high oxidation state.

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