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Byju's Answer
Standard XII
Chemistry
Heat of Reaction
For the react...
Question
For the reaction :
H
2
(
g
)
+
C
l
2
(
g
)
→
2
H
C
l
;
Δ
H
=
−
44
k
c
a
l
. What is the enthalpy of decomposition of
H
C
l
?
A
+ 44 kcal/mol
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B
- 44 kcal/mol
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C
- 22 kcal/mol
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D
+22 kcal/mol
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Solution
The correct option is
D
+22 kcal/mol
H
2
(
g
)
+
C
l
2
(
g
)
⟶
2
H
C
l
;
Δ
H
=
−
44
k
c
a
l
∴
2
H
C
l
⟶
H
2
(
g
)
+
C
l
2
(
g
)
;
Δ
H
=
44
k
c
a
l
Therefore, enthalpy of decomposition of 2 moles of
H
C
l
=
44
kcal
Therefore, enthalpy of decomposition of
H
C
l
=
44
2
k
c
a
l
/
m
o
l
e
=
+
22
k
c
a
l
/
m
o
l
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Similar questions
Q.
H
2
+
C
l
2
→
2
H
C
l
;
Δ
H
=
−
44
k
c
a
l
.
Heat of formation of
H
C
l
is:
Q.
C
(
s
)
+
O
2
(
g
)
→
C
O
2
,
(
g
)
;
Δ
H
=
−
94.3
kcal/mol
C
O
(
g
)
+
1
2
O
2
(
g
)
→
C
O
2
(
g
)
;
Δ
H
=
−
67.4
kcal/mol
O
2
(
g
)
→
2
O
(
g
)
;
Δ
H
=
117.4
kcal/mol
C
O
(
g
)
→
C
(
g
)
+
O
(
g
)
;
Δ
H
=
230.6
kcal/mol.
Calculate
Δ
H
for
C
(
s
)
→
C
(
g
)
in kcal/mol.
Q.
The average Xe - F bond energy is 34 kcal/mol, first I.E. of Xe is 279 kcal/mol, electron affinity of F is 85 kcal/mol and bond dissociation energy of
F
2
is 38 kcal/mol. Then, the enthalpy change for the reaction
X
e
F
4
→
X
e
+
+
F
−
+
F
2
+
F
will be
Q.
C
(
s
)
+
O
2
(
g
)
→
C
O
2
(
g
)
;
Δ
H
=
−
94.3
kcal/mol
C
O
(
g
)
+
1
/
2
O
2
(
g
)
→
C
O
2
(
g
)
;
Δ
H
=
−
67.4
kcal/mol
O
2
(
g
)
→
2
O
(
g
)
;
Δ
H
=
117.4
kcal/mol
C
O
(
g
)
→
C
(
g
)
+
O
(
g
)
;
Δ
H
=
230.6
kcal/mol
Calculate
Δ
H
for
C
(
s
)
→
C
(
g
)
in Kcal/mol.
Q.
For the decomposition of
1
mole of sodium chlorate, determine
Δ
H
r
e
a
c
t
i
o
n
.
(
Δ
H
0
f
values:
N
a
C
l
O
3
(
s
)
=
−
85.7
kcal
/
mol,
N
a
C
l
(
s
)
=
−
98.2
kcal
/
mol,
O
2
(
g
)
=
0
kcal
/
mol).
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