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Question

from the structures given below answer the following questions
1) CH3-CH2-CH(OH)-CH3
2) (CH3)2-C(OH)-CH3
3) CH3-CH2-CH2-CH2-OH
4)CH3-O(CH3)-CH-CH3
5)CH3-CH2-O-CH2-CH3
6)CH3-CH(CH3)-CH2-OH
A) THE PAIR OF COMPOUNDS THAT REPRESENTS CHAIN ISOMERISM
B)THE PAIR OF COMPOUNDS THAT REPRESENTS POSITION ISOMERISM
C)THE PAIR OF COMPOUNDS WHICH ARE FUNCTIOANALGROUP ISOMERS
D)THE COMPOUNDS THAT FORMS PAIRS OF METAMERS.

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Solution

a) Chain isomerism - differ in the carbon chain. CH3-CH2-CH2-CH2-OH and CH3-CH(CH3)-CH2-OH n-butyl alcohol and isobutyl alcoholStrucutre 3 and 6 are chain isomerismb) Position isomerism - differ in the position of the functional groupCH3-CH2-CH(OH)-CH3 and CH3-CH2-CH2-CH2-OH2-butanol and 1 -butanolStrucutre 1 and 3 are postional isomerismc) Functional isomerism - differ with functional groupAlcohols are functioal isomer with ether. Strucutre 1,2,3 and 6 are functional isomerism with 4 and 5d) Metamer - By shifting of alkyl group different structures are produced. Strucutre 4 and 5 are metamer

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