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Question

Geometrical isomerism is shown by:

A
CC
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B
>C=C<
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C
CC
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D
None of these
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Solution

The correct option is B >C=C<

A-Alkane, B- Alkene, C-Alkyne

Geometric Isomerism results most commonly from C=C. The important property which introduces the feature is the inability of the Carbon atoms to rotate relative to one another about the double bond. This is due specifically to the π bond but I won't discuss this part of the subject further on this site. The lack of rotation means the same groups can be attached in different ways to achieve diastereomers.

The molecules have identical connectivity so can't be described as structural isomers. There are two ways to name compounds of this kind. When two of the four groups attached to the carbons involved are hydrogen, the cis and trans notation can be used. When the other two constituents are on the same side of the molecules name is given the prefix cis. Otherwise if the constituents are on opposite sides, the prefix is trans.

Option B is correct.


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