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Question

How is methoxyethane prepared from:
(a) Methyl iodide (b) Diazomethane

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Solution

Methoxyethane, also known as ethyl methyl ether, is an ethyl group with a bonded methoxy. Methoxyethane is a colourless gaseous ether with a medicine-like odour. It is extremely flammable, and its inhalation may cause asphyxiation or dizziness. As a Lewis base, it can react with Lewis acids to form salts and reacts violently with oxidizing agents.

a) Preparation of Dimethyl ether (Methoxymethane) from methyl iodide :

When methyl iodide is heated with alcoholic sodium methoxide, it gives dimethyl ether.

CH3ONa + ICH3 Δ CH3OCH3 + NaI

b) Methoxyethane from diazomethane :

When ethyl alcohol is treated with diazomethane in presence of fluoroboric acid, methoxyethane is fromed.

C2H5OH + CH2N2 Δ−−HBF4C2H5OCH3 + N2


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