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Question
How many isomers of C4H10O reacts with CH3MgBr to evolve CH4 gas ? (Excluding stereoisomer)
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Solution
The isomers of C4H10O should have acidic hydrogen on reaction with CH3MgBr to evolve CH4 gas. All the isomers will be alcohols. Isomers are:1. CH3CH2CH2CH2−δ−O−δ+H2. CH3−CH2−CH|−δ−O−δ+H CH33. CH3−CH|−CH2−δ−O−δ+H CH3 CH34. H3C−|C|−δ−O−δ+H CH3
1. CH3CH2CH2CH2−δ−O−δ+H
2. CH3−CH2−CH|−δ−O−δ+H
CH3
3. CH3−CH|−CH2−δ−O−δ+H
CH3
CH3
4. H3C−|C|−δ−O−δ+H
CH3
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