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Standard XII
Chemistry
Preparation of Alcohols from Grignard Reagents
How the follo...
Question
How the following conversions can be carried out?
ethanol to but
−
1
−
yne
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Solution
C
H
3
C
H
2
−
O
H
e
t
h
a
n
o
l
S
O
C
l
2
−
−−−
→
C
H
3
C
H
2
−
C
l
H
C
≡
C
N
a
−
−−−−−
→
C
H
3
C
H
2
C
≡
C
H
b
u
t
−
1
−
y
n
e
In the given reaction, ethanol is first treated with
S
O
C
l
2
to give ethyl chloride.
When ethyl chloride is treated with sodium acetylide it gives but-1-yne.
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