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Question

Identify Z in the following reaction series.
CH3.CH2CH2Braq.NaOH(X)Al2O3Heat(Y)HOCl(Z)

A
mixture of CH3CClHCClH2 and CH3COHHCOHH2
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B
CH3COHHCClH2
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C
CH3CClHCOHH2
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D
CH3CClHCClH2
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Solution

The correct option is C CH3CClHCOHH2
When 1-bromopropane is treated with aq NaOH, propan-1-ol (compound X) is obtained. Bromide is replaced with OH group.
When propan-1-ol is heated in presence of alumina, propene (compound Y) is obtained due to dehydration.
When propene is treated with HOCl (chlorine water), 2-chloropropan-1-ol (compound Z) is obtained.
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