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Question

If E0Fe2+/Fe = 0.441 V and E0Fe3+/Fe2+ = 0.771 V, the standard EMF of the reaction,

FE+2FE3+3FE2+ will be:

A
0.330V
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B
1.653V
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C
1.212V
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D
0.111V
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Solution

The correct option is C 1.212V
FeFe+2+2eE0Fe/Fe2+

2Fe+3+2e2Fe+2E0Fe3+/Fe2+

The above are the half cell reaction for the cell.

From here we can observe

Eocell=EoFe/Fe+2+EoFe+3/Fe+2

=(0.441)+(0.771)

=1.212V

Hence, the correct option is C

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