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Question

If M(g) M+(g)+e;ΔH=100eVM(g) M2+(g)+2e;ΔH=250 eV
Which is/are correct statement(s)?
(IE= ionization energy, ΔHge= electron gain enthalpy)

A
IE1 of M(g) is 100 eV
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B
IE1 of M+(g) is 150 eV
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C
IE2 of M(g) is 250 eV
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D
ΔHge of M2+(g) is -150 eV
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Solution

The correct options are
A IE1 of M(g) is 100 eV
B IE1 of M+(g) is 150 eV
D ΔHge of M2+(g) is -150 eV
IE1 for M+ is actually IE2

M+(g)M+2(g)+e

IE2=(250100) eV=150 eV
Since, IE=EA
Hence,
ΔHge(M2+)=IE2=150 eV

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