If S+O2→SO2,△H=−298.2kJmole−1 SO2+1/2O2→SO3,△H=−98.7kJmole−1 SO3+H2O→H2SO4,△H=−130.2kJmole−1 H2+1/2O2→H2O,△H=−287.3kJmole−1 the enthalpy of formation of H2SO4 at 298K will be ?
A
−814.4kJmole−1
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B
+814.4kJmole−1
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C
−650.3kJmole−1
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D
−433.7kJmole−1
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Solution
The correct option is A−814.4kJmole−1
S+O2→SO2ΔH=−298.2kJ/mole
SO2+12O2→SO3ΔH=−98.7kJ/mole
SO3+H2O→H2SO4ΔH=−130.2kJ/mole
H2+12O2→H2OΔH=−287.3kJ/mole
The formation of H2SO4
H2+S+2O2→H2SO4 can be calculated by adding the above four equations