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Question

If S+O2SO2,H=298.2 kJ mole1
SO2+1/2O2SO3,H=98.7 kJ mole1
SO3+H2OH2SO4,H=130.2 kJ mole1
H2+1/2O2H2O,H=287.3 kJ mole1
the enthalpy of formation of H2SO4 at 298 K will be ?

A
814.4 kJ mole1
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B
+814.4 kJ mole1
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C
650.3 kJ mole1
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D
433.7 kJ mole1
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Solution

The correct option is A 814.4 kJ mole1
S+O2SO2ΔH=298.2 kJ/mole

SO2+12O2SO3ΔH=98.7 kJ/mole

SO3+H2OH2SO4ΔH=130.2 kJ/mole

H2+12O2H2OΔH=287.3 kJ/mole

The formation of H2SO4

H2+S+2O2H2SO4 can be calculated by adding the above four equations

ΔH=(298.2+98.7+130.2+287.3)=814.4 kJ/mole

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