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Question

If the equilibrium constant for A ⇌ B + C is Keq (1) and that of B + C ⇌ P is Keq (2), the equilibrium constant for A ⇌ P is


A

Keq (1) Keq (2)

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B

Keq (2) − Keq (!)

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C

Keq (!) + Keq (2)

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D

Keq (1) / Keq (2)

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Solution

The correct option is A

Keq (1) Keq (2)


Solution:

  • In Equation A ⇌ B + C
  • Equilibrium constant Keq (1) =([B] + [C]) / [A]
  • In Equation B + C ⇌ P
  • Equilibrium constant Keq (2) = [P] / ([B] + [C])
  • As B+C ⇌P and A ⇌P, So A ⇌B+C ⇌P
  • Therefore, for A ⇌P, Equilibrium constant will be Keq (1) Keq (2)

The correct answer is option A.


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