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Question

In acidic medium (Conc. H2SO4),Hydrogen peroxide reacts with K2Cr2O7 in the presence of ether forms a deep violet coloured chromium peroxide. The Oxidation state of chromium in chromium pentoxide is


A

+2

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B

+3

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C

+5

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D

+6

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Solution

The correct option is D

+6


H2O2→ H2O + [O]

K2Cr2O7 +4[O] → H2Cr2O7 +K2SO4

H2Cr2O7 +4[O] →2CrO5 +H2O

4CrO5 +6H2SO4 → 2Cr2(SO4)3 +6H2O +7O2

CrO5 is blue in colour and has a butterfly structure. There are 2 peroxy linkages on either side of the Cr and one Cr=O bond.


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