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Question

In one experiment 100 mL of ozonised oxygen was reduced to 60 mL when treated with turpentine oil. What would be increase in volume if the original sample was heated until no further change occured [All volumes are measured under identical condition].

A
10 mL
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B
20 mL
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C
30 mL
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D
40 mL
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Solution

The correct option is A 10 mL
Given : In one experiment 100 mL100 mL of ozonised oxygen was reduced to 60 mL60 mL when treated with turpentine oil. What would be increase in volume if the original sample was heated until no further change occured [All volumes are measured under identical condition].

Solution :
100 ml of mixture contain O3 and O2.
Turpentine oil absorb only O3.
Since reduction in volume is 20 mL indicates that mixture contain 20 mL of O3. It means 100 mL of mixture contains 20 ml O3 and 80 ml O2. .
On Heating O3 decomposed as follows :
2O3 ​ 3 O2
2 ml O3 gives 3 ml O2.
Therefore 20 mL of would give 30 mL of O2.
​Total volume of mixture after heatO3ng
​80 mL of O2. + 30 mL of O2. = 110 mL
​The total increase in volume = 110mL-100 mL
​ = 10 mL

The Correct Opt = A

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