The correct option is C [Cu(H2O)4]2+,H2CO3
According to Bronsted- lowry acid concept acids are ions or molecules which have tendency to donate protons.
[Cu(H2O)4]2+ will donate a proton to HCO−3
so, HCO−3 (base) changes to H2CO3(acid)
hence both [Cu(H2O)4]2+ and H2CO3 behaving as a bronsted- lowry acid.