In the reaction, BrO3−(aq.)+5Br−(aq.)+6H+(aq.)⟶3Br2(l)+3H2O(l). The rate of appearance of bromine (Br2) is related to rate of disappearance of bromide ions as following:
A
d[Br2]dt=25d[Br−]dt
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B
d[Br2]dt=−35d[Br−]dt
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C
d[Br2]dt=−53[Br−]dt
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D
d[Br2]dt=+53d[Br−]dt
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Solution
The correct option is Dd[Br2]dt=−35d[Br−]dt −15ddt[Br−]=13ddt[Br2]ddt[Br2]=−35ddt[Br−]