In which of the following dimer empty atomic orbital of central atom of monomer does not involve in hybridisation?

G a_{2} H_{6}

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A l_{2} B r_{6}

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B e_{2} H_{4}

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C l_{2} O_{6}

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Solution

The correct option is C $C l_{2} O_{6}$
Dichlorine hexoxide is the chemical compound with the molecular formula $C l_{2} O_{6}$ , which is correct for its gaseous state. However, in liquid or solid form, this chlorine oxide ionizes into the dark red ionic compound chloryl perchlorate $[C l O_{2}]^{+} [C l O_{4}]^{-}$ , which may be thought of as the mixed anhydride of chloric and perchloric acids.

$G a_{2} H_{6}, A l_{2} B r_{6}, B e_{2} H_{4}$ have no empty orbital only in $C l_{2} O_{6}$ $C l$ has empty orbital and $C l_{2} O_{6}$ dimer empty atomic orbital of central atom of monomer does not involve in hybridisation.

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