In which of the following equilibrium equation Kp>Kc?
A
2SO3(g)⇌2SO2(g)+O2(g)
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B
PCl3(g)+Cl2⇌PCl5(g)
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C
H2(g)+I2(g)⇌2Hl(g)
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D
N2(g)+3H2(g)→2NH3(g)
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Solution
The correct option is A2SO3(g)⇌2SO2(g)+O2(g) Kp=Kc(RT)Δn where Δn= (number of gaseous products) − (No. of gaseous reactants) So, for KP>KC Δn≥1 Here, 2SO3⇋2SO2+O2 Has Δn=3−2=1 So, for this reaction KP>KC