Match the following:-
$\begin{matrix} L I S T - I & L I S T - I I (P) P C l_{3} F_{2}, P C l_{2} F_{3} & (1) H y b r i d i s a t i o n o f c e n t r a l a t o m - s a m e, s h a p e o f m o l e c u l e - s a m e, d i p o l e m o m e n t - s a m e (Q) B F_{3}, B C l_{3} & (2) H y b r i d i s a t i o n o f C e n t r a l a t o m - s a m e, s h a p e o f, m o l e c u l e - s a m e, d i p o l e m o m e n t - s a m e i s o e l e c t r o n i c s p e c i e s, u s e d i n f e r t i l i s e r p r e p a r a t i o n (R) C O_{2}, C N_{2}^{- 2} & (3) H y b r i d i s a t i o n o f c e n t r a l a t o m - s a m e, s h a p e o f m o l e c u l e - s a m e, d i p o l e m o m e n t - s a m e, i s o e l e c t r o n i c s p e c i e s, a r o m a t i c (S) C_{6} H_{6}, B_{3} N_{3} H_{6} & (4) H y b r i d i s a t i o n o f c e n t r a l a t o m - s a m e, s h a p e o f m o l e c u l e - s a m e, d i p o l e m o m e n t - d i f f e r e n t \end{matrix}$

(Q-1),(R-2)

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(R-1)(S-3)

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(Q-4),(R-2)

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(P-1),(S-3)

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Solution

The correct option is A (Q-1),(R-2)
$P$ Hybridisation is $S p^{3} d,$ shape of molecule is Trigonal bi pyramidal but $μ$ is not same
$Q$ Hyb is $S p^{2}$ , Trigonal planar and $μ = 0$
$R$ Hyb is Sp, linear, $μ = 0,$ have same electrons (22) and used in the preparation of fertiliser $(N H_{3})$
$S$ Hyb is $S p^{2},$ planar, $μ = 0$ Isoelectronic and aromatic with Huckel's rule.

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Similar questions

Q. Match the following:-

\begin{matrix} L I S T - I & L I S T - I I (P) P C l_{3} F_{2}, P C l_{2} F_{3} & (1) H y b r i d i s a t i o n o f c e n t r a l a t o m - s a m e, s h a p e o f m o l e c u l e - s a m e, d i p o l e m o m e n t - s a m e (Q) B F_{3}, B C l_{3} & (2) H y b r i d i s a t i o n o f C e n t r a l a t o m - s a m e, s h a p e o f, m o l e c u l e - s a m e, d i p o l e m o m e n t - s a m e i s o e l e c t r o n i c s p e c i e s, u s e d i n f e r t i l i s e r p r e p a r a t i o n (R) C O_{2}, C N_{2}^{- 2} & (3) H y b r i d i s a t i o n o f c e n t r a l a t o m - s a m e, s h a p e o f m o l e c u l e - s a m e, d i p o l e m o m e n t - s a m e, i s o e l e c t r o n i c s p e c i e s, a r o m a t i c (S) C_{6} H_{6}, B_{3} N_{3} H_{6} & (4) H y b r i d i s a t i o n o f c e n t r a l a t o m - s a m e, s h a p e o f m o l e c u l e - s a m e, d i p o l e m o m e n t - d i f f e r e n t \end{matrix}

Q. Match the following:-

\begin{matrix} L I S T - I & L I S T - I I (P) P C l_{3} F_{2}, P C l_{2} F_{3} & (1) H y b r i d i s a t i o n o f c e n t r a l a t o m - s a m e, s h a p e o f m o l e c u l e - s a m e, d i p o l e m o m e n t - s a m e (Q) B F_{3}, B C l_{3} & (2) H y b r i d i s a t i o n o f C e n t r a l a t o m - s a m e, s h a p e o f, m o l e c u l e - s a m e, d i p o l e m o m e n t - s a m e i s o e l e c t r o n i c s p e c i e s, u s e d i n f e r t i l i s e r p r e p a r a t i o n (R) C O_{2}, C N_{2}^{- 2} & (3) H y b r i d i s a t i o n o f c e n t r a l a t o m - s a m e, s h a p e o f m o l e c u l e - s a m e, d i p o l e m o m e n t - s a m e, i s o e l e c t r o n i c s p e c i e s, a r o m a t i c (S) C_{6} H_{6}, B_{3} N_{3} H_{6} & (4) H y b r i d i s a t i o n o f c e n t r a l a t o m - s a m e, s h a p e o f m o l e c u l e - s a m e, d i p o l e m o m e n t - d i f f e r e n t \end{matrix}

Q. Match the following:-

\begin{matrix} L I S T - I & L I S T - I I (P) P C l_{3} F_{2}, P C l_{2} F_{3} & (1) H y b r i d i s a t i o n o f c e n t r a l a t o m s a m e, s h a p e o f m o l e c u l e s a m e, d i p o l e m o m e n t s a m e (Q) B F_{3}, B C l_{3} & (2) H y b r i d i s a t i o n o f C e n t r a l a t o m s a m e, s h a p e o f, m o l e c u l e s a m e, d i p o l e m o m e n t s a m e i s o e l e c t r o n i c s p e c i e s, u s e d i n f e r t i l i s e r p r e p a r a t i o n (R) C O_{2}, C N_{2}^{- 2} & (3) H y b r i d i s a t i o n o f c e n t r a l a t o m s a m e, s h a p e o f m o l e c u l e s a m e, d i p o l e m o m e n t s a m e, i s o e l e c t r o n i c s p e c i e s, a r o m a t i c (S) C_{6} H_{6}, B_{3} N_{3} H_{6} & (4) H y b r i d i s a t i o n o f c e n t r a l a t o m s a m e, s h a p e o f m o l e c u l e s a m e, b u t d i p o l e m o m e n t d i f f e r e n t \end{matrix}

$\begin{matrix} LIST-I & LIST-II (P) P C l_{3} F_{2}, P C l_{2} F_{3} & (1) Hybridisation of central atom same, shape of molecule same, dipole moment same (Q) B F_{3}, B C l_{3} & (2) Hybridisation of Central atom same, shape of molecule same, dipole moment same, isoelectronic species, used in fertiliser preparation (R) C O_{2} C N_{2}^{- 2} & (3) Hybridisation of central atom same, shape of molecule same, dipole moment same, isoelectronic species, aromatic (S) C_{6} H_{6}, B_{3} N_{3} H_{6} & (4) Hybridisation of central atom same, shape of molecule same, but dipole moment different \end{matrix}$

Q. Which of the following sets of molecules have different shape but same hybridisation of the central atoms?

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