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Question

Mention the condition favoring ionic bond formation.


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Solution

Understanding ionic bond:

  • An ionic bond or electrovalent bond is formed due to the electrostatic force of attraction between a cation and an anion.

Condition for the formation of Ionic Bond:

  • Sublimation energy is required by solid metal to form individual gaseous atoms. Low sublimation energy favors the formation of an ionic compound.
  • Ionization energy is required by the gaseous metal atom to release an electron and become a metal ion. Low ionization energy favors the formation of an ionic compound.
  • Bond dissociation enthalpy is required by the non-metallic gaseous molecule to form an individual gaseous non-metallic atom. Low bond dissociation enthalpy favors the formation of an ionic compound.
  • The gaseous non-metallic atom accepts electrons and releases energy. This energy is called electron gain enthalpy. High electron gain enthalpy favors the formation of an ionic compound.
  • The cation and anion now unite to form a crystal lattice. During the formation of a crystal lattice, lattice energy is released. High lattice energy favors the formation of an ionic compound.

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