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Reduction of Carboxylic Acids

NO2-CH2-CH=CH...

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NO2-CH2-CH=CH2 +HBr\overset{}{→ NO2-CH2-CHBr-CH3(Minor) +NO2-CH2-CH2-CH3Br (major)} why 2nd product is majo

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C H_{2} = C H - N O_{2} + H B r \to P

; The major product

^{'} P^{'}

$C H_{3} O - C H = C H - N O_{2}$	$I$
$C H_{2} = C H - N O_{2}$	$I I$
$C H_{2} = C H - C l$	$I I I$
$C H_{2} = C H_{2}$	$I V$

Which of the following is the correct order of

C = C

bond lengths among these compounds?

C H_{2} = C H - N O_{2} + H B r \to P

; The major product

^{'} P^{'}

Q. Out of which

N O_{2} - C H_{2} - C H_{2} - O^{⊖}

C H_{3} - C H_{2} - C H_{2} - O^{⊖}

which one is more stable and why?

$C H_{2} | C l - O H$ is more acidic than $C H_{2} | N O_{2} - C H_{2} - O H$

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