On heating water, bubbles being formed at the bottom of the vessel detach and rise. Take the bubbles to be spheres of radius R and making a circular contact of radius with the bottom of the vessel. If r << R and the surface tension of water is T, the value of r just before bubbles detach is (density of water is ρw).
R2√2ρwg3T
Force due to excess pressure = Upthrust
⇒2TR(πr2)=4π3R3ρwg∴r=R2√2ρwg3T